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Transformations of Peroxide Products from Ozonolysis of (–)-α-Pinene and (+)-3-Carene by Capric and Benzoic Acid Hydrazides
Chemistry of Natural Compounds ( IF 0.8 ) Pub Date : 2020-03-01 , DOI: 10.1007/s10600-020-03002-5
Yu. V. Myasoedova , L. R. Garifullina , E. R. Nurieva , N. M. Ishmuratova , G. Yu Ishmuratov

Reduction of the peroxide ozonolysis products of (–)-α-pinene and (+)-3-carene by capric and benzoic acid hydrazides in CH2Cl2 or THF produced diacylhydrazones either pure or mixed with the corresponding ketoacids. The capric acid diacylhydrazone formed primarily in CH2Cl2; benzoic acid diacylhydrazone, in THF. The only reaction products formed in MeOH were the corresponding ketoesters.

中文翻译:

癸酸和苯甲酸酰肼臭氧分解 (–)-α-蒎烯和 (+)-3-Carene 转化过氧化物产物

用癸酸和苯甲酸酰肼在 CH2Cl2 或 THF 中还原 (-)-α-蒎烯和 (+)-3-carene 的过氧化物臭氧分解产物,产生纯的或与相应酮酸混合的二酰基腙。癸酸二酰腙主要在 CH2Cl2 中形成;苯甲酸二酰腙,在四氢呋喃中。在 MeOH 中形成的唯一反应产物是相应的酮酯。
更新日期:2020-03-01
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