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Nanoindentation and tribology of ZrB2 based luminescent ceramics
Journal of the European Ceramic Society ( IF 5.7 ) Pub Date : 2020-03-31 , DOI: 10.1016/j.jeurceramsoc.2020.03.021
Michal Ivor , David Medved , Marek Vojtko , Annamaria Naughton-Duszova , Lukasz Marciniak , Jan Dusza

Nano-mechanical and wear characteristics of ZrB2 + Al2O3:Cr3+,Nd3+ (Al2O3 co-doped with Cr3+ and Nd3+ ions) luminescent ceramic composites have been investigated using nanoindentation and tribological tests. Nanoindentation was carried out using a Berkovich diamond tip applying continuous stiffness measuring (CSM) mode with a maximum depth of 200 nm. The wear behaviour was studied during dry sliding in the air with a SiC counter body at applied loads of 5 and 50 N, and sliding speed of 0.1 m/s. The nanohardness of the ZrB2 and Al2O3 are very similar with mean values of 34.2 GPa and 32.6 GPa, respectively The Young modulus for ZrB2 is higher with a mean value of 555.6 GPa in comparison to the Young modulus of alumina with mean value of 473.8 GPa. Pop – in effect was found during the indentation of ZrB2 grains at indentation loads from 0.2–8.0 mN. The lowest coefficient of friction was measured for ZrB2 + 8%Al2O3:Cr3+,Nd3+ at 5 N load with value of approximately 0.5. The wear rate of the system ZrB2 + 32 % Al2O3:Cr3+,Nd3+ at 5 N is significantly lower in comparison to the wear rate of ZrB2 + 8% Al2O3:Cr3+,Nd3+ but at a load of 50 N the wear of the systems is very similar approximately 1. 10−5 mm3/N.m. Tribolayer formation connected with debris origin, oxidation and tribochemical reactions were characteristic for both composites with similar chemical composition but different size and thickness of tribolayers.



中文翻译:

ZrB 2基发光陶瓷的纳米压痕和摩擦学

利用纳米压痕和摩擦学研究了ZrB 2 + Al 2 O 3:Cr 3+,Nd 3+(Al 2 O 3与Cr 3+和Nd 3+离子共掺杂)的纳米力学和磨损特性。测试。使用Berkovich金刚石尖端进行纳米压痕,该尖端采用连续硬度测量(CSM)模式,最大深度为200 nm。在SiC相对体在5和50 N的外加载荷以及0.1 m / s的滑动速度下,在空气中干式滑动期间研究了磨损行为。ZrB 2和Al 2 O 3的纳米硬度与氧化铝的杨氏模量平均值为473.8 GPa相比,ZrB 2的杨氏模量较高,平均值分别为34.2 GPa和32.6 GPa。在压入载荷为0.2–8.0 mN的ZrB 2晶粒压入过程中发现了爆裂声。在5 N负载下,ZrB 2 + 8%Al 2 O 3:Cr 3+,Nd 3+的最低摩擦系数为0.5。系统ZrB 2 + 32%Al 2 O 3:Cr 3+,Nd 3+的磨损率在5 N被显著相比的ZrB的磨损率降低2 + 8%的Al 2 ö 3:铬3+,钕3+但在50载荷N的系统的磨损是非常相似的大约1 10 - 5  mm 3 / Nm摩擦层的形成与碎屑的产生,氧化和摩擦化学反应有关,是两种化学成分相似但摩擦层大小和厚度不同的复合材料的特征。

更新日期:2020-03-31
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