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PEDOT: PSS hydrogel film for supercapacitors via AlCl3-induced cross-linking and subsequent organic solvent treatments
Materials Today Communications ( IF 3.7 ) Pub Date : 2020-04-01 , DOI: 10.1016/j.mtcomm.2020.101090
Dawei Xu , Xiaojie Feng , Dongmei Niu , Xufei Zhu , Ye Song

An ionically crosslinked conducting polymer poly (3, 4-ethylenedioxythiophene): poly (4-styrenesulfonate) (PEDOT: PSS) hydrogel was synthesized by fast gelation of PEDOT: PSS dispersion (PH1000) using a high concentration of Al3+ (2 M) with a high water content of 94.4 wt% and three-dimensional interconnected networks. The highly conductive PEDOT: PSS hydrogel film was achieved by soaking it in ethylene glycol (EG) for a certain time. It was found for the first time that the conductivity of the PEDOT: PSS hydrogel film can be further improved with the vapors of m-cresol. It delivers 158 F g−1 at a scan rate of 50 mV s−1 with an outstanding rate capability and good cycling stability with 84.9% capacitance retention after 2000 cycles.



中文翻译:

PEDOT:通过AlCl 3诱导的交联和后续有机溶剂处理的超级电容器用PSS水凝胶膜

离子交联的导电聚合物聚(3,4-乙撑二氧噻吩):聚(4-苯乙烯磺酸盐)(PEDOT:PSS)水凝胶是通过使用高浓度的Al 3+(2 M ),水分含量高达94.4 wt%,并具有三维互连网络。高导电性的PEDOT:PSS水凝胶薄膜是通过将其浸泡在乙二醇(EG)中一定时间而制成的。首次发现,间甲酚蒸汽可进一步提高PEDOT:PSS水凝胶膜的电导率。它以50 mV s -1的扫描速率提供158 F g -1,具有出色的速率能力和良好的循环稳定性,在2000次循环后电容保持率为84.9%。

更新日期:2020-04-01
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