Abstract Chiral cobalt metal–organic framework based on peptide with aspartic acid as building block has been synthesized and characterized by FTIR, TGA, DSC, SEM, TEM, BET and X-ray diffraction analysis. The catalytic activity of Co-P-MOFs was applide for asymmetric sulfoxidative cross-coupling using poly sulfinylpiperazine as a novel sulfoxide transfer reagent. The Co-P-MOF canberecycled several times without lossinactivity.

中文翻译：

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手性钴-肽金属-有机骨架（Co-P-MOF）：作为使用聚亚磺酰基哌嗪进行不对称亚磺氧化交叉偶联反应的高效且可重复使用的多相催化剂

摘要 合成了以天冬氨酸为结构单元的基于肽的手性钴金属-有机骨架，并通过 FTIR、TGA、DSC、SEM、TEM、BET 和 X 射线衍射分析对其进行了表征。Co-P-MOFs 的催化活性适用于使用聚亚磺酰基哌嗪作为新型亚砜转移试剂的不对称亚砜氧化交叉偶联。Co-P-MOF 可以循环多次而不会失去活性。