当前位置: X-MOL 学术Tetrahedron › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Aryne-mediated transformations of 5-perfluorophenyl-substituted 3-(pyridin-2-yl)-1,2,4-triazines in the design of novel 10-(1H-1,2,3-triazol-1-yl)pyrido[1,2-a]indole fluorophores
Tetrahedron ( IF 2.1 ) Pub Date : 2020-04-01 , DOI: 10.1016/j.tet.2020.131147
Timofey D. Moseev , Mikhail V. Varaksin , Igor A. Lavrinchenko , Alexey P. Krinochkin , Dmitry S. Kopchuk , Grigory V. Zyryanov , Pavel A. Slepukhin , Oleg N. Chupakhin , Valery N. Charushin

A number of novel fluorinated derivatives of the family of pyrido [1,2-a]indole fluorophores have first been synthesized via the aryne-mediated domino transformations of 5-(perfluorophenyl)-3-(pyridin-2-yl)-1,2,4-triazines. A comprehensive study of photophysical properties of the obtained polyfluoroaryl substituted derivatives, in which polyfluoroaryl, 1,2,3-triazole, and pyridoindole subunits contribute to a joint chromophore system, has shown that these compounds proved to exhibit a fluoresce with green light in acetonitrile solutions.



中文翻译:

新颖的10-(1 H -1,2,3-三唑-1-基)设计中5-全氟苯基取代的3-(吡啶-2-基)-1,2,4-三嗪的芳烃介导转化吡啶并[1,2- a ]吲哚荧光团

吡啶[1,2-a]吲哚荧光团家族的许多新型氟化衍生物已首先通过芳烃介导的5-(全氟苯基)-3-(吡啶-2-基)-1的多米诺转化合成, 2,4-三嗪。对所获得的多氟芳基取代的衍生物(其中多氟芳基,1,2,3-三唑和吡啶并吲哚亚基有助于共同的生色团系统)的光物理性质的全面研究表明,这些化合物在乙腈中被证明具有绿色荧光。解决方案。

更新日期:2020-04-01
down
wechat
bug