Scalable Electrochemical Transition‐Metal‐Free Dehydrogenative Cross‐Coupling Amination Enabled Alkaloid Clausines Synthesis,Advanced Synthesis & Catalysis

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Scalable Electrochemical Transition‐Metal‐Free Dehydrogenative Cross‐Coupling Amination Enabled Alkaloid Clausines Synthesis
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-03-30 , DOI: 10.1002/adsc.202000228
Pan Zhang ₁ , Baoying Li ₁ , Liwei Niu ₁ , Ling Wang ₁ , Guofeng Zhang ₁ , Xiaofei Jia ₂ , Guoying Zhang ₂ , Siyuan Liu ₁ , Li Ma ₁ , Wei Gao ₁ , Dawei Qin ₁ , Jianbin Chen ₁

Affiliation

Reported herein is an environmentally benign electrochemical C−H bond dehydrogenative amination protocol for the construction of privileged carbazole moiety with broad generality. Preliminary mechanistic investigations implied a radical reaction pathway. Compared with traditional ionic routes, the scalable transition‐metal and exogenous‐oxidant free strategy highlighted the green and sustainable nature of this method.

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