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Magnesium Borohydride Ammonia Borane as a Magnesium Ionic Conductor
ACS Applied Energy Materials ( IF 5.4 ) Pub Date : 2020-03-31 00:00:00 , DOI: 10.1021/acsaem.0c00113 Kazuaki Kisu 1 , Sangryun Kim 2 , Munehiro Inukai 3 , Hiroyuki Oguchi 1 , Shigeyuki Takagi 2 , Shin-ichi Orimo 1, 2
ACS Applied Energy Materials ( IF 5.4 ) Pub Date : 2020-03-31 00:00:00 , DOI: 10.1021/acsaem.0c00113 Kazuaki Kisu 1 , Sangryun Kim 2 , Munehiro Inukai 3 , Hiroyuki Oguchi 1 , Shigeyuki Takagi 2 , Shin-ichi Orimo 1, 2
Affiliation
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Magnesium borohydride ammonia borane, Mg(BH4)2(NH3BH3)2, was electrochemically investigated. Impedance measurements of the mechanochemically synthesized Mg(BH4)2(NH3BH3)2 exhibited an ionic conductivity of 1.3 × 10–5 S cm–1 at 30 °C. Electrochemical cells fabricated with Mg(BH4)2(NH3BH3)2 as the solid electrolyte demonstrated reversible Mg migration through the material, indicating its potential for use as a Mg ionic conductor in all-solid-state Mg-ion batteries.
中文翻译：
硼氢化镁氨硼烷作为镁离子导体
电化学研究了硼氢化镁氨硼烷Mg（BH 4）2（NH 3 BH 3）2。机械化学合成的Mg（BH 4）2（NH 3 BH 3）2的阻抗测量在30°C下具有1.3×10 –5 S cm –1的离子电导率。用Mg（BH 4）2（NH 3 BH 3）2制成的电化学电池 因为固体电解质显示出可逆的Mg迁移通过该材料，表明其在全固态Mg离子电池中用作Mg离子导体的潜力。
更新日期：2020-03-31
中文翻译：
硼氢化镁氨硼烷作为镁离子导体
电化学研究了硼氢化镁氨硼烷Mg（BH 4）2（NH 3 BH 3）2。机械化学合成的Mg（BH 4）2（NH 3 BH 3）2的阻抗测量在30°C下具有1.3×10 –5 S cm –1的离子电导率。用Mg（BH 4）2（NH 3 BH 3）2制成的电化学电池 因为固体电解质显示出可逆的Mg迁移通过该材料，表明其在全固态Mg离子电池中用作Mg离子导体的潜力。
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