Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K,Journal of Chemical & Engineering Data

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Experimental Data on Chemical Equilibrium in the System with Ethyl Formate Synthesis Reaction at 298.15 K
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2020-03-30 , DOI: 10.1021/acs.jced.9b01205
Artemiy Samarov ₁ , Maya Trofimova ₁ , Maria Toikka ₁ , Alexander Toikka ₁

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Chemical equilibrium (CE) in the quaternary reacting system formic acid–ethanol–ethyl formate–water was experimentally studied at 298.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography analysis. The obtained data gave an opportunity to present the disposition of the surface of CE in a composition tetrahedron. The constants of CE (“concentration” and thermodynamic) were determined on the base of experimental data and UNIFAC model.

中文翻译：

298.15 K时甲酸乙酯合成反应体系中化学平衡的实验数据。

在298.15 K和大气压下，通过实验研究了甲酸-乙醇-甲酸乙酯-水四元反应体系中的化学平衡（CE）。通过气相色谱分析确定CE组成。获得的数据提供了呈现CE表面在组合物四面体中的布置的机会。根据实验数据和UNIFAC模型确定CE的常数（“浓度”和热力学）。

更新日期：2020-03-30

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