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Nickel‐Catalyzed Reductive Coupling of Aldehydes with Alkynes Mediated by Alcohol†
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-03-28 , DOI: 10.1002/cjoc.201900543
Yan‐Long Zheng 1 , Mengchun Ye 1
Affiliation  

A nickel‐catalyzed reductive coupling of aldehydes with alkynes using 1‐phenylethanol as reducing agent has been developed. The key achievement of this work is that we demonstrate environmentally benign 1‐phenylethanol can serve as a viable alternative reducing agent to Et3B, ZnEt2 and R3SiH for the nickel‐catalyzed reductive coupling reaction of aldehyde and alkynes.

中文翻译:

酒精介导的镍与醛催化的醛还原还原偶联†

已经开发了使用1-苯基乙醇作为还原剂的镍与炔烃的镍催化还原偶联反应。这项工作的关键成果是,我们证明了对环境无害的1-苯基乙醇可以作为Et 3 B,ZnEt 2和R 3 SiH的可行替代还原剂,用于镍催化的醛与炔烃的还原偶联反应。
更新日期:2020-04-22
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