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Highly selective hydrosilylation of equilibrating allylic azides.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-03 , DOI: 10.1039/d0cc01316a Ruzhang Liu 1 , Zhen Wei , Juan Wang , Yongmei Liu , Huaiguo Xue
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-03 , DOI: 10.1039/d0cc01316a Ruzhang Liu 1 , Zhen Wei , Juan Wang , Yongmei Liu , Huaiguo Xue
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The Pt-catalyzed hydrosilylation of equilibrating allylic azides is reported. The reaction provides only one out of four possible hydrosilylation products in good yields and with very high chemoselectivity (alk-1-ene vs. alk-2-ene), regioselectivity (linear vs. branched), and excellent functional group tolerance.
中文翻译:
平衡烯丙基叠氮化物的高度选择性氢化硅烷化。
报道了平衡的烯丙基叠氮化物的Pt催化的氢化硅烷化。该反应仅以良好的收率提供了四种可能的氢化硅烷化产物中的一种,并且具有非常高的化学选择性(烷-1-烯对烷-2-烯),区域选择性(直链对支链)和出色的官能团耐受性。
更新日期:2020-03-27
中文翻译:
平衡烯丙基叠氮化物的高度选择性氢化硅烷化。
报道了平衡的烯丙基叠氮化物的Pt催化的氢化硅烷化。该反应仅以良好的收率提供了四种可能的氢化硅烷化产物中的一种,并且具有非常高的化学选择性(烷-1-烯对烷-2-烯),区域选择性(直链对支链)和出色的官能团耐受性。