Chemical Physics Letters ( IF 2.8 ) Pub Date : 2020-03-27 , DOI: 10.1016/j.cplett.2020.137412 Yu Jiao , Mengna Zhang , Bo Qin , Kaige Hou , Yanze Du , Jinghong Ma , Ruifeng Li
Zeolite Y nanocrystal assembly was synthesized by using cetyltrimethyl ammonium bromide (CTAB) under low gelling and aging temperature in the hydrothermal system. XRD, SEM, N2 adsorption/desorption isotherms, 29Si and 27Al MAS NMR spectra as well as NH3-TPD demonstrated that the synthesized zeolite Y is a mesoporous zeolite composed of well-developed nanocrystals with high external surface area, intercrystal mesoporosity and acidity. The conversions of 1,3,5-trimethylbenzene (TMB) and 1,3,5-triisopropylbenzene (TIPB) reflect its superior features for isomerization, selectivity of bulky molecule and catalytic stability.
中文翻译:
CTAB在低胶凝和时效温度下合成的纳米Y分子筛分子
十六烷基三甲基溴化铵(CTAB)在低胶凝和老化温度下在水热体系中合成了Y型沸石分子筛。XRD,SEM,N 2吸附/解吸等温线,29 Si和27 Al MAS NMR光谱以及NH 3 -TPD证明合成的沸石Y是由发达的纳米晶体组成的介孔沸石,该纳米晶体具有高的外表面积,晶间介孔性和酸度。1,3,5-三甲基苯(TMB)和1,3,5-三异丙基苯(TIPB)的转化反应了其出色的异构化,大分子选择性和催化稳定性。