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Catalyst‐Free Electrosynthesis of Benzimidazolones through Intramolecular Oxidative C−N Coupling
Advanced Synthesis & Catalysis ( IF 5.4 ) Pub Date : 2020-03-26 , DOI: 10.1002/adsc.202000198
Jiang‐Sheng Li 1 , Pan‐Pan Yang 1 , Xin‐Yun Xie 1 , Si Jiang 1 , Li Tao 2 , Zhi‐Wei Li 1 , Cui‐Hong Lu 1 , Wei‐Dong Liu 3
Affiliation  

The electrochemical synthesis of N, N’‐disubstituted benzimidazolones from ureas through an intramolecular anodic dehydrogenative N−H/C−H coupling has been developed. The reaction undergoes under the undivided electrolysis conditions and obviates the need for any catalysts and chemical oxidants.

中文翻译:

分子内氧化C-N偶联无催化剂电合成苯并咪唑酮

已经开发了通过分子内阳极脱氢NH / CH偶联从尿素中电化学合成NN'-二取代的苯并咪唑酮的方法。该反应在未分开的电解条件下进行,并且不需要任何催化剂和化学氧化剂。
更新日期:2020-03-26
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