Magneto-Chiral Dichroism: A Playground for Molecular Chemists.,Chemistry - A European Journal

当前位置： X-MOL 学术 › Chem. Eur. J. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Magneto-Chiral Dichroism: A Playground for Molecular Chemists.
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2020-03-27 , DOI: 10.1002/chem.202000937
Matteo Atzori ₁ , Geert L J A Rikken ₁ , Cyrille Train ₁

Affiliation

Magneto‐chiral dichroism (MChD) is a non‐reciprocal manifestation of light–matter interaction that can be observed in chiral systems possessing a magnetization, either spontaneous or induced by an external magnetic field. It features a differential absorption or emission of unpolarized light that depends on the relative orientation of the magnetization with respect to the direction of the light propagation vector and on the absolute configuration of the system. Molecular chemistry is the best‐suited route towards systems combining chirality and magnetism. Nowadays, investigation of MChD is still in its infancy although this effect might play a fundamental role in technological applications, such as optical readout of magnetic data with unpolarized light. With this Minireview, the authors provide a precise description of this unconventional effect, recall the main results obtained so far and, highlighting new challenges, underline the opportunities opened to molecular chemists interested in investigating this fascinating effect with implications in chemistry and beyond.

中文翻译：

磁手性二色性：分子化学家的游乐场。

磁手性二色性（MChD）是光与物质相互作用的一种非互惠的表现，可以在具有自发性或由外部磁场引起的磁化的手性体系中观察到。它具有非偏振光的差分吸收或发射特性，该吸收或发射取决于磁化强度相对于光传播矢量方向的相对方向以及系统的绝对配置。分子化学是将手性和磁性相结合的系统的最佳途径。如今，MChD的研究仍处于起步阶段，尽管这种影响可能在技术应用中起着根本性的作用，例如用非偏振光光学读取磁性数据。通过这次Minireview，作者对这种非常规的影响提供了精确的描述，

更新日期：2020-03-27

点击分享查看原文

点击收藏

阅读更多本刊最新论文