Mechanochemistry: an efficient and versatile toolbox for synthesis, transformation, and functionalization of porous metal–organic frameworks,CrystEngComm

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Mechanochemistry: an efficient and versatile toolbox for synthesis, transformation, and functionalization of porous metal–organic frameworks
CrystEngComm ( IF 2.6 ) Pub Date : 2020-03-27 , DOI: 10.1039/d0ce00091d
Tomislav Stolar _{1,

2,

3} , Krunoslav Užarević _{1,

2,

3}

Affiliation

Mechanochemistry is nowadays recognized as a green approach to chemical synthesis, but the full scope of the accompanying solid-state reactivity is just beginning to be unravelled. This is especially true for the preparation of porous metal–organic frameworks, whose synthesis by the use of mechanical force lagged behind that of other relevant classes of materials. Nevertheless, mechanochemical procedures have rapidly evolved from a mere synthetic curiosity towards efficient methods for obtaining high-quality MOFs on different scales. This Highlight is dedicated to the functional approach of using mechanochemistry for the preparation of catalytically active MOF composites and mixed-metal and mixed-ligand MOFs with synergistic properties as well as fine-tuning of the MOF performance via defect engineering and amorphization.

中文翻译：

机械化学：多孔金属-有机骨架的合成，转化和功能化的高效通用工具箱

如今，机械化学被认为是化学合成的一种绿色方法，但是伴随的固态反应性的全部范围才刚刚被弄清楚。对于多孔金属有机骨架的制备尤其如此，其利用机械力的合成落后于其他相关材料类别。然而，机械化学方法已从单纯的好奇心迅速发展为获得不同规模的高质量MOF的有效方法。该重点内容专门介绍了使用机械化学方法制备具有催化性能的MOF复合材料以及具有协同性能的混合金属和混合配体MOF的功能方法，以及通过以下方法对MOF性能进行微调的方法缺陷工程和非晶化。

更新日期：2020-03-27

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