Nitroprusside as a promising building block to assemble an organic-inorganic hybrid for thermo-responsive switching materials.,Chemical Communications

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Nitroprusside as a promising building block to assemble an organic-inorganic hybrid for thermo-responsive switching materials.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-05-21 , DOI: 10.1039/d0cc01877e
Rong-Guan Qiu ₁ , Xiao-Xian Chen ₁ , Rui-Kang Huang ₁ , Dong-Dong Zhou ₁ , Wei-Jian Xu ₂ , Wei-Xiong Zhang ₁ , Xiao-Ming Chen ₁

Affiliation

We present a new hybrid compound, namely (Me2NH2)[KFe(CN)5(NO)], possessing a unique nitroprusside-based inorganic host framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds and synchronously deformed inorganic framework give rise to thermal-responsive switching behaviours on both thermal expansion and nonlinear optical properties during the phase transition at around room temperature.

中文翻译：

硝普钠作为有前途的基石，可以组装用于热敏开关材料的有机-无机混合物。

我们提出了一种新的杂化化合物，即（Me2NH2）[KFe（CN）5（NO）]，在包裹有机客体阳离子的4连接sra拓扑结构中具有独特的基于硝普钠的无机主体框架。柔性的客体-氢键和同步变形的无机骨架在室温附近的相变过程中，在热膨胀和非线性光学性质方面都产生了热响应转换行为。

更新日期：2020-03-27

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