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Are ionic liquids and liquid coordination complexes really different? - Synthesis, characterization, and catalytic activity of AlCl3/base catalysts.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-05-19 , DOI: 10.1039/d0cc01452d Rajkumar Kore 1 , Steven P Kelley 1 , Anand D Sawant 1 , Manish Kumar Mishra 1 , Robin D Rogers 2
Chemical Communications ( IF 4.3 ) Pub Date : 2020-05-19 , DOI: 10.1039/d0cc01452d Rajkumar Kore 1 , Steven P Kelley 1 , Anand D Sawant 1 , Manish Kumar Mishra 1 , Robin D Rogers 2
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Lewis acid/base catalysts of AlCl3/N-methyl-2-pyrrolidone (O-NMP) and AlCl3/1-methylimidazole (N-Mim) were prepared and found to have higher catalytic activity in the Friedel-Crafts alkylation of benzene than the known super acidic ionic liquid chloroaluminate [HN222][Al2Cl7] ([HN222]+ = triethylammonium). Crystals structures were obtained for AlCl3(N-Mim), [AlCl2(O-NMP)2][AlCl4], and [Al(O-NMP)6][AlCl4]3·(C6H6)3 supporting the assignments of neutral and charged catalytic species.
中文翻译：
离子液体和液体配位络合物真的不同吗？-AlCl3 /碱催化剂的合成，表征和催化活性。
制备了AlCl3 / N-甲基-2-吡咯烷酮（O-NMP）和AlCl3 / 1-甲基咪唑（N-Mim）的路易斯酸/碱催化剂，发现该催化剂在苯的Friedel-Crafts烷基化反应中具有较高的催化活性。已知的超酸性离子液体氯铝酸盐[HN222] [Al2Cl7]（[HN222] + =三乙铵）。获得了AlCl3（N-Mim），[AlCl2（O-NMP）2] [AlCl4]和[Al（O-NMP）6] [AlCl4] 3·（C6H6）3的晶体结构，支持中性和中性分配带电的催化物质。
更新日期：2020-03-27
中文翻译：
离子液体和液体配位络合物真的不同吗？-AlCl3 /碱催化剂的合成，表征和催化活性。
制备了AlCl3 / N-甲基-2-吡咯烷酮（O-NMP）和AlCl3 / 1-甲基咪唑（N-Mim）的路易斯酸/碱催化剂，发现该催化剂在苯的Friedel-Crafts烷基化反应中具有较高的催化活性。已知的超酸性离子液体氯铝酸盐[HN222] [Al2Cl7]（[HN222] + =三乙铵）。获得了AlCl3（N-Mim），[AlCl2（O-NMP）2] [AlCl4]和[Al（O-NMP）6] [AlCl4] 3·（C6H6）3的晶体结构，支持中性和中性分配带电的催化物质。
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