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A facile synthesis, structural and triple-luminescence properties of a novel fluoroperovskite RbCaF3: Sm3+ phosphor for radiation dosimetry and orange-red LED applications
Materials Science and Engineering: B ( IF 3.9 ) Pub Date : 2020-03-27 , DOI: 10.1016/j.mseb.2020.114531
Arumugam Raja , R. Nagaraj , K. Ramachandran , V. Sivasubramani , G. Annadurai , D. Joseph Daniel , P. Ramasamy

Polycrystalline compounds of Rubidium Calcium Fluoride doped with samarium were synthesized by conventional high temperature solid state reaction method. Phase purity of the title compound was analyzed by PXRD study. The presence of functional groups has been identified by FTIR. The morphology of as-synthesized phosphor was analyzed by FE-SEM. Presence of metal ions was confirmed using EDAX study. The sharp PL emission was obtained at 599 nm under the excitations of 402 nm and 469 nm. The luminescence decay profile time was analysed. The Commission Internationale del’Eclairage (CIE) chromaticity coordinates of Sm3+ doped RbCaF3 phosphor were found to be 0.495 and 0.483. The thermoluminescence property of X-ray irradiated RbCaF3:0.6Sm3+ phosphor was analyzed by TL reader. The TL glow curve peak originated at 258° C. Order of kinetics, activation energy, symmetry factor and frequency factor were calculated by Chen’s method. X-ray-induced luminescence was recorded and corresponding dominant emission peak is 603 nm.



中文翻译:

新型氟钙钛矿RbCaF 3:Sm 3+荧光粉的简便合成,结构和三重发光性质,用于辐射剂量学和橙红色LED应用

采用常规高温固相反应法合成了掺sa的氟化Fluor多晶化合物。通过PXRD研究分析标题化合物的相纯度。FTIR已确定官能团的存在。通过FE-SEM分析了合成后的磷光体的形态。使用EDAX研究确认了金属离子的存在。在402 nm和469 nm的激发下,在599 nm处获得了清晰的PL发射。分析了发光衰减曲线时间。发现掺杂Sm 3+的RbCaF 3荧光粉的国际照明委员会(CIE)色度坐标为0.495和0.483。X射线辐射的RbCaF 3:0.6Sm 3+的热致发光性质荧光粉通过TL读取器分析。TL辉光曲线峰起源于258℃。通过Chen方法计算动力学,活化能,对称因子和频率因子的顺序。记录X射线诱导的发光,并且相应的主要发射峰为603nm。

更新日期:2020-03-27
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