Molybdenum-Promoted Dearomatization of Pyridines,Organometallics

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Molybdenum-Promoted Dearomatization of Pyridines
Organometallics ( IF 2.5 ) Pub Date : 2020-03-27 , DOI: 10.1021/acs.organomet.0c00047
Justin H. Wilde ₁ , Jeffery T. Myers ₁ , Diane A. Dickie ₁ , W. Dean Harman ₁

Affiliation

A second-row transition metal complex {MoTp(NO)(DMAP)} (DMAP = 4-(dimethylamino)pyridine; Tp = tris(pyrazolyl)borate) is shown to form dihapto-coordinate complexes with a range of substituted pyridines bearing both electron-withdrawing and electron-donating substituents. Subsequent reactivity of the pyridine ligand is demonstrated by protonation and nucleophilic addition reactions.

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