The composite adsorbent of natural mesoporous powder of Wakkanai siliceous shale (WSS) impregnated with LiCl has been investigated. In this study, the slurry of WSS–LiCl with acryl resin as a binder was prepared for fabricating an adsorbent-filled heat exchanger (HEX). The optimal LiCl content for the impregnation with WSS was 20 wt%, which was chosen from the relation between water uptake and pore volume. The theoretical sorption amounts were estimated from various sorption isotherms, and the value was 0.34 g/g at the temperature conditions of 80 °C (regeneration), 30 °C (condensation and adsorption), and 15 °C (evaporation). From the analysis of sorption heat, it was found that water adsorption and desorption occurred repeatedly at the lower region of 45–50 kJ/mol at the driving conditions for the adsorption heat pump. To evaluate the coefficient of cooling performance (COP) and a specific cooling power (SCP), the adsorbent-filled HEX was prepared using a small-sized corrugated-fin-type aluminum HEX and the slurry. The COP and SCP were 0.41 and 498 W/kg at 80 °C of regeneration, respectively.

研究了浸渍有LiCl的稚内硅质页岩（WSS）天然中孔粉末的复合吸附剂。在本研究中，制备了以丙烯酸树脂为粘合剂的WSS-LiCl浆料，以制造填充有吸附剂的热交换器（HEX）。WSS浸渍的最佳LiCl含量为20 wt％，这是从吸水率和孔体积之间的关系中选择的。根据各种吸附等温线估算理论吸附量，在80°C（再生），30°C（冷凝和吸附）和15°C（蒸发）的温度条件下，该值为0.34 g / g。通过对吸附热的分析，发现在吸附热泵的驱动条件下，水的吸附和解吸在45-50 kJ / mol的较低区域反复发生。为了评估冷却性能系数（COP）和比冷却功率（SCP），使用小型波纹翅片型铝HEX和浆料制备了填充有吸附剂的HEX。在80°C的再生温度下，COP和SCP分别为0.41和498 W / kg。