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Unprecedented reductive cyclisation of salophen ligands to tetrahydroquinoxalines during metal complex formation.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-30 , DOI: 10.1039/d0cc01192d
Katie J Lamb 1 , Mark R Dowsett , Michael North , Rachel R Parker , Adrian C Whitwood
Affiliation  

The synthesis of novel tetrahydroquinoxalines by a metal induced one-electron reductive cyclisation of salophen ligands was found to occur when a salophen ligand was treated with chromium(ii) chloride or decamethylcobaltocene.

中文翻译:

在金属配合物形成过程中,史洛芬配体前所未有地还原环化成四氢喹喔啉。

当通过氯化铬(ii)或十甲基钴茂金属对Salophen配体进行处理时,发现通过金属诱导的Salophen配体的单电子还原环化反应合成了新的四氢喹喔啉。
更新日期:2020-03-25
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