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Solvent-driven migration of highly polar monomers into hydrophobic PDMS produces a thick graft layer via subsurface initiated ATRP for efficient antibiofouling.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-03 , DOI: 10.1039/d0cc00768d
Xin Yu 1 , Yang Yang , Wufang Yang , Xungai Wang , Xin Liu , Feng Zhou , Yan Zhao
Affiliation  

The sucessful grafting of highly polar polymer chains both on the surface and in the subsurface of PDMS via subsurface initiated ATRP for the improved antibiofouling performance is enabled by the diffusion of organic solvents (in a water-based binary solvent) which act as not only a "carrier" for hydrophilic monomers but also a "sweller" for the PDMS substrate.

中文翻译:

溶剂驱动的高极性单体向疏水性PDMS的迁移通过地下引发的ATRP产生了一层厚厚的接枝层,从而有效地防止了生物积垢。

有机溶剂的扩散(在水基二元溶剂中)不仅可以使有机溶剂扩散,还可以通过次表面引发的ATRP将PDMS表面和次表面的高极性聚合物链成功接枝到PDMS的表面和表面,以提高抗污性能。亲水单体的“载体”,而PDMS底物的“膨胀剂”。
更新日期:2020-03-25
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