Collective coupling between vibrations of molecules, participating in reaction, and the vacuum field of a microfluidic optical cavity is now considered to be one of the novel potential unconventional ways of influencing the reaction rate. Herein, this effect is theoretically analyzed focusing on adiabatic reactions occurring via the ground electronic state with a saddle point located between reactants and products. The key conclusion is that for cavities with a relatively large number of reactants ($\sim {10}^6-{10}^7$) the scales of the corresponding corrections of the pre-exponential factor and activation energy are nearly negligible.

中文翻译：

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腔中的真空场，光介导的振动耦合和化学反应性

分子的振动，参与反应和微流体光学腔的真空场之间的集体耦合现在被认为是影响反应速率的新型潜在非常规方法之一。在此，从理论上分析了这种效应，重点是通过基态电子状态发生的绝热反应，该绝热反应的鞍点位于反应物和产物之间。关键结论是对于反应物数量相对较大的型腔（$〜{10}^6--{10}^7$）对指数前因子和活化能的相应校正量几乎可以忽略不计。