The first enantioselective method for the installation of the SCF3 group at the C-4 position of azlactones is described in the present communication under quinidinium phase transfer catalysis. The higher performance of substrates containing electron-rich 2-aryl groups at the azlactone was rationalized using DFT calculations.

中文翻译：

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手性相转移催化下a酸酯的不对称三氟甲基硫醇化。

在喹啉鎓相转移催化下的本说明书中描述了将SCF3基团安装在a内酯的C-4位的第一种对映选择性方法。使用DFT计算合理化了含氮杂内酯中富含电子的2-芳基的底物的较高性能。