First imidazole-fused carbaporphyrinoid and its conversion to a N-heterocyclic carbene precursor.,Chemical Communications

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First imidazole-fused carbaporphyrinoid and its conversion to a N-heterocyclic carbene precursor.
Chemical Communications ( IF 4.3 ) Pub Date : 2020-04-30 , DOI: 10.1039/d0cc01013h
Demin Ren ₁ , Sebastian Koniarz , Xiaofang Li , Piotr J Chmielewski

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A series of novel imidazole-fused carbaporphyrinoids were obtained by a surprisingly simple approach by exploiting the reaction of tosylmethylisocyanide (TOSMIC) with readily obtainable 2-aza-21-carbaporphyrins. A facile methylation of silver(iii) complexes of these fused systems leads to cationic N-heterocyclic carbene precursors.

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