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Aerobic synthesis of N-sulfonylamidines mediated by N-heterocyclic carbene copper(I) catalysts
Beilstein Journal of Organic Chemistry ( IF 2.2 ) Pub Date : 2020-03-24 , DOI: 10.3762/bjoc.16.43
Faïma Lazreg , Marie Vasseur , Alexandra M Z Slawin , Catherine S J Cazin

A new catalytic strategy for the one-pot synthesis of N-sulfonylamidines is described. The cationic copper(I) complexes were found to be highly active and efficient under mild conditions in air and in the absence of solvent. A copper acetylide is proposed as key intermediate in this transformation.

中文翻译:

N-杂环卡宾铜(I)催化剂介导的N-磺酰lam的好氧合成

描述了一种用于一锅合成N-磺酰胺基的新催化策略。发现阳离子铜(I)络合物在温和条件下在空气中和没有溶剂的情况下具有很高的活性和效率。提出了乙炔铜作为该转化的关键中间体。
更新日期:2020-03-24
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