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A facile one-pot flash combustion synthesis of La@ZnO nanoparticles and their characterizations for optoelectronic and photocatalysis applications
Journal of Photochemistry and Photobiology A: Chemistry ( IF 4.1 ) Pub Date : 2020-03-20 , DOI: 10.1016/j.jphotochem.2020.112465
Kamlesh V. Chandekar , Mohd. Shkir , Aslam Khan , Badria M. Al-Shehri , Mohamed S. Hamdy , S. AlFaify , Mohamed Ahmed El-Toni , Ali Aldalbahi , Anees A. Ansari , Hamid Ghaithan

The successful one pot flash combustion synthesis of ZnO nanoparticles (NPs) with a diverse LA (La@ZnO) content was achieved simply and economically. X-ray diffraction confirms the synthesis of ZnO with a hexagonal crystal system. The vibrational bands are positioned at 100, 332, 380, 438 and 583 cm−1 for pure and La@ZnO NPs. FESEM images exhibit roughly spherical and oval morphologies of pure ZnO with particles size 120 nm and La@ZnO NPs with particle sizes in the 46–74 nm range. The particle size of a La doped ZnO sample increases with increase in concentration from 1.0 % to 7.5 wt.% of La. The evaluated energy gap of La doped ZnO NPs decreased from 3.220 to 3.210 eV as the concentration of La varied from 1.0–7.5 wt.% as estimated by Kubelka–Munk theory. The photocatalytic analysis of the as-synthesized ZnO nanoparticles is maximized at La (1.0 wt.%) and the mechanism of photocatalytic decolourization reaction is discussed. The results suggest that the La-doped ZnO nanoparticles can be used in optoelectronic and photocatalytic applications.



中文翻译:

La @ ZnO纳米粒子的快速一锅快速燃烧合成及其表征,用于光电和光催化应用

简单,经济地完成了具有不同LA(La @ ZnO)含量的ZnO纳米颗粒(NPs)的成功的一锅快速燃烧合成。X射线衍射证实了具有六方晶体体系的ZnO的合成。振动带位于100、332、380、438和583 cm -1处用于纯和La @ ZnO NP。FESEM图像显示了粒径为120 nm的纯ZnO和粒径在46–74 nm范围内的La @ ZnO NP的大致球形和椭圆形形态。La掺杂的ZnO样品的粒径随La的浓度从1.0%增加到7.5 wt。%而增加。随着La的浓度从1.0–7.5变化,La掺杂的ZnO NPs的能隙从3.220降低到3.210 eV。由Kubelka-Munk理论估算的重量百分比。合成后的ZnO纳米粒子的光催化分析在La(1.0 wt。%)时达到最大,并讨论了光催化脱色反应的机理。结果表明,La掺杂的ZnO纳米颗粒可用于光电和光催化应用。

更新日期:2020-03-20
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