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An efficient hydrocyanation of α, β-unsaturated diesters with TMSCN catalyzed by MgI2 etherate
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2019-12-09 , DOI: 10.1080/10426507.2019.1700377 Haokun Pan 1 , Hua Li 1 , Huijun Liu 1 , Xingxian Zhang 1
Phosphorus, Sulfur, and Silicon and the Related Elements ( IF 1.4 ) Pub Date : 2019-12-09 , DOI: 10.1080/10426507.2019.1700377 Haokun Pan 1 , Hua Li 1 , Huijun Liu 1 , Xingxian Zhang 1
Affiliation
Abstract A mild, efficient and highly regioselective addition of trimethylsilyl cyanide (TMSCN) to α,β-unsaturated diesters has been achieved by using MgI2 etherate as catalyst under solvent-free conditions. This protocol provides the corresponding β-cyano esters in high yields. Graphical Abstract
中文翻译：
MgI2 醚合物催化 α, β-不饱和二酯与 TMSCN 的高效氢氰化反应
摘要 以MgI2 醚合物为催化剂，在无溶剂条件下，实现了三甲基氰化硅烷(TMSCN) 温和、高效和高区域选择性加成到α,β-不饱和二酯的过程。该协议以高产率提供相应的 β-氰基酯。图形概要
更新日期：2019-12-09
中文翻译：
MgI2 醚合物催化 α, β-不饱和二酯与 TMSCN 的高效氢氰化反应
摘要 以MgI2 醚合物为催化剂，在无溶剂条件下，实现了三甲基氰化硅烷(TMSCN) 温和、高效和高区域选择性加成到α,β-不饱和二酯的过程。该协议以高产率提供相应的 β-氰基酯。图形概要
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