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Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines
Green Chemistry ( IF 9.3 ) Pub Date : 2020-03-19 , DOI: 10.1039/d0gc00570c Uttam Kumar Das 1, 2, 3, 4 , Trevor Janes 1, 2, 3, 4 , Amit Kumar 1, 2, 3, 4 , David Milstein 1, 2, 3, 4
Green Chemistry ( IF 9.3 ) Pub Date : 2020-03-19 , DOI: 10.1039/d0gc00570c Uttam Kumar Das 1, 2, 3, 4 , Trevor Janes 1, 2, 3, 4 , Amit Kumar 1, 2, 3, 4 , David Milstein 1, 2, 3, 4
Affiliation
Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.
中文翻译:
锰催化的环状酰亚胺选择性加氢成二醇和胺
在这里,我们报道了环状酰亚胺选择性加氢成二醇和胺,这是第一次由富含地球的金属的络合物锰夹杂物进行均相催化。基于合理的机理实验,提出了合理的催化循环。
更新日期:2020-03-19
中文翻译:
锰催化的环状酰亚胺选择性加氢成二醇和胺
在这里,我们报道了环状酰亚胺选择性加氢成二醇和胺,这是第一次由富含地球的金属的络合物锰夹杂物进行均相催化。基于合理的机理实验,提出了合理的催化循环。