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Fabrication of ZnO@Ag@Ag3PO4 Ternary Heterojunction: Superhydrophilic Properties, Antireflection and Photocatalytic Properties
Micromachines ( IF 3.0 ) Pub Date : 2020-03-15 , DOI: 10.3390/mi11030309
Huan Huan , Huge Jile , Yijun Tang , Xin Li , Zao Yi , Xiang Gao , Xifang Chen , Jian Chen , Pinghui Wu

A ZnO seed layer was formed on the fluorine-doped tin oxide substrate by magnetron sputtering, and then a ZnO nanorod was grown on the ZnO seed layer by a hydrothermal method. Next, we prepared a single-crystal Ag seed layer by magnetron sputtering to form a composite heterostructure. Finally, Ag3PO4 crystals were grown on the Ag seed layer by a stepwise deposition method to obtain a [email protected]@Ag3PO4 ternary heterojunction. The composite heterostructure of the material has super strong hydrophilicity and can be combined with water-soluble pollutants very well. Besides, it has excellent anti-reflection performance, which can absorb light from all angles. When Ag exists in the heterojunction, it can effectively improve the separation of photo-generated electrons and holes, and improve the photoelectric conversion performance. Based on the above characteristics, this nano-heterostructure can be used in the fields of solar cells, sensors, light-emitting devices, and photocatalysis. View Full-Text

中文翻译:

ZnO @ Ag @ Ag3PO4三元异质结的制备:超亲水性能,抗反射和光催化性能

通过磁控溅射在掺​​杂氟的氧化锡衬底上形成ZnO籽晶层,然后通过水热法在ZnO籽晶层上生长ZnO纳米棒。接下来,我们通过磁控溅射制备了单晶Ag籽晶层,以形成复合异质结构。最后,通过逐步沉积法在Ag种子层上生长Ag 3 PO 4晶体,以获得[电子邮件保护] @Ag 3 PO 4三元异质结。该材料的复合异质结构具有超强的亲水性,可以很好地与水溶性污染物结合。此外,它具有出色的抗反射性能,可以吸收所有角度的光。当Ag存在于异质结中时,可以有效地改善光生电子和空穴的分离,并提高光电转换性能。基于上述特征,该纳米异质结构可用于太阳能电池,传感器,发光器件和光催化领域。查看全文
更新日期:2020-03-20
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