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Muon spin relaxation study of phosphosilicate gels
Solid State Ionics ( IF 3.0 ) Pub Date : 2020-03-12 , DOI: 10.1016/j.ssi.2020.115287
Serena Esposito , Nigel J. Clayden , Stephen P. Cottrell

Muon dynamics in phosphosilicate proton conductors P2O5-SiO2 with a composition 30 mol% phosphorus oxide (30P) have been studied as a function of temperature using muon spin relaxation. For materials heat treated at 300 °C the muons implant at sites close to P-OH groups associated with water molecules. While in 1000 °C heat treated samples the muons are trapped at sites involving a bridging oxygen P-O-Si. Averaging of the local nuclear dipolar field by dynamics of the adsorbed water is observed above ca 180 K for the muon sites in the 300 °C heat treated sample. There is some evidence for further muon dynamics in this material above 250 K perhaps caused by muon diffusion.



中文翻译:

磷硅酸盐凝胶的Muon自旋弛豫研究

使用μ子自旋弛豫技术研究了磷硅酸盐质子导体P 2 O 5 -SiO 2组成为30 mol%氧化磷(30P)时的μ子动力学随温度的变化。对于在300°C下进行了热处理的材料,μ子会在与水分子相关的P-OH基团附近的位置植入。在1000°C的热处理过的样品中,μ子被捕获在涉及桥接氧PO-Si的位置。对于300°C热处理过的样品中的介子部位,在大约180 K以上,通过吸附水的动力学观察到局部核偶极场的平均值。有证据表明,这种材料在250 K以上可能会进一步引起介子扩散,这可能是由介子扩散引起的。

更新日期:2020-03-12
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