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Hydrothermal liquefaction of macroalgae: Influence of zeolites based catalyst on products
Journal of the Energy Institute ( IF 5.7 ) Pub Date : 2019-06-23 , DOI: 10.1016/j.joei.2019.06.007
Chuantao Ma , Jiguo Geng , Dong Zhang , Xuefeng Ning

Hydrothermal liquefaction (HTL) of Ulva prolifera macroalgae (UP) was carried out in the presence of three zeolites based catalysts (ZSM-5, Y-Zeolite and Mordenite) with the different weight percentage (10–20 wt%) at 260–300 °C for 15–45 min. A comparison between non-catalytic and catalytic behavior of ZSM-5, Y-Zeolite, and Mordenite in the conversion of Ulva prolifera showed that is affected by properties of zeolites. Maximum bio-oil yield for non-catalytic liquefaction was 16.6 wt% at 280 °C for 15 min. The bio-oil yield increased to 29.3 wt% with ZSM-5 catalyst (15.0 wt%) at 280 °C. The chemical components and functional groups present in the bio-oils are identified by GC-MS, FT-IR, 1H-NMR, and elemental analysis techniques. Higher heating value (HHV) of bio-oil (32.2–34.8 MJ/kg) obtained when catalyst was used compared to the non-catalytic reaction (21.2 MJ/kg). The higher de-oxygenation occurred in the case of ZSM-5 catalytic liquefaction reaction compared to the other catalyst such as Y-zeolite and mordenite. The maximum percentage of the aromatic proton was observed in bio-oil of ZSM-5 (29.7%) catalyzed reaction and minimum (1.4%) was observed in the non-catalyst reaction bio-oil. The use of zeolites catalyst during the liquefaction, the oxygen content in the bio-oil reduced to 17.7%. Aqueous phase analysis exposed that presence of valuables nutrients.



中文翻译:

大型藻的水热液化:沸石基催化剂对产物的影响

Ulva prolifera macroalgae(UP)的水热液化(HTL)在三种沸石基催化剂(ZSM-5,Y-沸石和丝光沸石)的存在下进行的,两种催化剂的重量百分比(10-20 wt%)在260-300 °C 15–45分钟。比较ZSM-5,Y-沸石和丝光沸石在Ulva增殖剂转化中的非催化和催化行为表明,它受沸石性能的影响。非催化液化的最大生物油产率在280°C下15分钟为16.6 wt%。在280°C下使用ZSM-5催化剂(15.0 wt%),生物油产率提高到29.3 wt%。生物油中存在的化学成分和官能团通过GC-MS,FT-IR,1进行鉴定1 H-NMR和元素分析技术。与非催化反应(21.2 MJ / kg)相比,使用催化剂时获得的生物油发热量(HHV)更高(32.2–34.8 MJ / kg)。与其他催化剂(例如Y沸石和丝光沸石)相比,在ZSM-5催化液化反应中发生的脱氧更高。在ZSM-5催化的生物油中观察到最大的芳香族质子百分比(29.7%),在非催化反应的生物油中观察到最小的1.4%。在使用液化过程中使用沸石催化剂时,生物油中的氧含量降低到17.7%。水相分析表明有价值的营养物质的存在。

更新日期:2019-06-23
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