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Dependence of thermodynamic properties of soft microgel on dynamics of glass transition
Journal of Non-Crystalline Solids ( IF 3.2 ) Pub Date : 2017-10-30 , DOI: 10.1016/j.jnoncrysol.2017.10.040
Arijit Mondal

Microgels suspended in liquid are found to be swollen significantly from their original radius. The microgel particle interacts through soft sphere repulsive interparticle potential 1/rn where n determines the hardness of interparticle potential. In present work the elastic response of soft colloids are studied. The ratio of high-frequency bulk modulus (K) and shear modulus (G) increases with volume fraction. The change of K/G or poison's ratio (ν) with their packing fraction is also discussed here. The equation of state describes relation between compressibility factor (Z) and the volume fraction (η) of soft microgel suspended in a liquid at constant temperature. The dynamics of relaxation of glass forming liquid is determined by a quantity called fragility. There is an apparent correlation between fragility (m) and the hardness of interparticle potential (n). In particular I focus on how m changes with n. A simple relationship between the low volume fraction activation energy of relaxation and the hardness of interparticle potential is determined from the low volume fraction estimation of fragility (m). The correlation between K/G with (1/n) is also reported here.



中文翻译:

软凝胶的热力学性质对玻璃化转变动力学的依赖

发现悬浮在液体中的微凝胶从其原始半径明显膨胀。微凝胶颗粒通过软球排斥的颗粒间电势1 / r n相互作用,其中n决定颗粒间电势的硬度。在目前的工作中,研究了软胶体的弹性响应。高频体积弹性模量(比率ķ )和剪切模量(G ^ )与体积分数增加。的变化ķ / g ^ 或毒药比(ν)与他们的敛集率也在这里讨论。状态方程描述了压缩系数(Z)与体积分数(η)之间的关系)悬浮在恒定温度下的液体中的柔软的微凝胶。玻璃形成液的弛豫动力学由称为脆性的量决定。脆性(m)与粒子间电势硬度(n)之间存在明显的相关性。我特别关注m随着n的变化。低体积分数的弛豫活化能和粒子间电势硬度之间的简单关系是由对脆性(m)的低体积分数估算得出的。之间的相关性ķ / g ^ 与(1 / n)也此处报告。

更新日期:2020-04-22
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