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Fabrication of helical SiO2@Fe–N doped C nanofibers and their applications as stable lithium ion battery anodes and superior oxygen reduction reaction catalysts
Electrochimica Acta ( IF 5.5 ) Pub Date : 2020-03-20 , DOI: 10.1016/j.electacta.2020.136107
Haoran Wang , Wenjun Cai , Shun Wang , Baozong Li , Yonggang Yang , Yi Li , Qi-Hui Wu

Helical silica nanofibers have been prepared based on a sol-gel transcription approach. After covering a layer of m-phenylenediamine formaldehyde resin and consequent carbonization, SiO2@Fe–N doped C nanofibers with C content of 33.7 wt% and N content of 3.86 wt% were produced successfully. When applied as the electrode material for lithium-ion batteries (LIBs), they exhibit a high reversible capacity of 1274 mA h g−1 in the 1000th cycle and superior rating capability, implying the possibility as outstanding candidate anode materials for LIBs. Additionally, owing to the doping of Fe2O3 and N, the nanofibers also exhibit a well-performed oxygen reduction reaction activity, which is comparable to the commercial Pt/C catalyst.



中文翻译:

螺旋SiO 2 @ Fe–N掺杂的C纳米纤维的制备及其作为稳定的锂离子电池阳极和优异的氧还原反应催化剂的应用

螺旋二氧化硅纳米纤维已经基于溶胶-凝胶转录方法制备。在覆盖了间苯二胺甲醛树脂层并随后碳化之后,成功生产了C含量为33.7 wt%,N含量为3.86 wt%的SiO 2 @ Fe–N掺杂的C纳米纤维。当用作锂离子电池(LIB)的电极材料时,它们在第1000个循环中表现出1274 mA h g -1的高可逆容量,并且具有出众的额定容量,这意味着有可能成为出色的LIB候选阳极材料。另外,由于Fe 2 O 3和N的掺杂,纳米纤维还表现出良好的氧还原反应活性,这与市售的Pt / C催化剂相当。

更新日期:2020-03-20
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