Synthesis of cis β‐Hydroxy Ketones by Desymmetrization of 1,3‐Cyclopentanediones through Ruthenium‐Catalyzed Hydrogen Transfer,Asian Journal of Organic Chemistry

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Synthesis of cis β‐Hydroxy Ketones by Desymmetrization of 1,3‐Cyclopentanediones through Ruthenium‐Catalyzed Hydrogen Transfer
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2020-03-31 , DOI: 10.1002/ajoc.202000121
Han Wang ₁ , Yang Zhao ₂ , Yi‐Xuan Ding ₂ , Chang‐Bin Yu ₂ , Yong‐Gui Zhou _{1,

2}

Affiliation

A facile synthesis of chiral cis β‐hydroxy ketones was successfully developed through ruthenium‐catalyzed transfer hydrogenative desymmetrization of 1,3‐cyclopentanedione. The experiment on gram scale could be performed without loss of reactivity and enantioselectivity.

中文翻译：