Direct Transformation of Arenols Based on C—O Activation,Chinese Journal of Chemistry

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Direct Transformation of Arenols Based on C—O Activation
Chinese Journal of Chemistry ( IF 5.5 ) Pub Date : 2020-03-18 , DOI: 10.1002/cjoc.201900506
Feng Liu _{1,

2} , Hao‐jun Jiang ₁ , Yi Zhou ₁ , Zhang‐jie Shi ₂

Affiliation

In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation.

中文翻译：

基于CO活化的戊烯醇的直接转化

考虑到衬底的可用性，直接使用芳烃作为交叉耦合的耦合伙伴，原子效率和成本将是最有吸引力的目标之一。迄今为止，已经进行了许多努力以不同的策略活化酚的C-O键，例如通过原位形成的中间体，通过催化还原性脱芳香化-缩合-重芳香化或催化脱氧来活化。在这篇综述中，我们总结了通过C-O活化在作为电子亲电子体的芳烃交叉偶联方面的最新进展。

更新日期：2020-03-18

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