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Zeolite membranes: Comparison in the separation of H2O/H2/CO2 mixtures and test of a reactor for CO2 hydrogenation to methanol
Catalysis Today ( IF 5.2 ) Pub Date : 2020-03-18 , DOI: 10.1016/j.cattod.2020.03.014
R. Raso , M. Tovar , J. Lasobras , J. Herguido , I. Kumakiri , S. Araki , M. Menéndez

A zeolite membrane reactor can be employed for hydrogenation of CO2 to methanol. The removal of water from the reaction environment would increase the reaction rate and the achievable conversion. The separation of water from mixtures containing CO2, hydrogen and water at suitable temperatures for this reaction was tested with several zeolite membranes (zeolite A, mordenite, zeolite T, chabazite and Ti-Chabazite). Zeolite A provided the best H2O/H2 separation factor. Preliminary experiments comparing a traditional reactor and the combination of a traditional reactor with a membrane reactor show that the yield of methanol was improved, in one case being higher than the limit corresponding to the thermodynamic equilibrium in a conventional reactor.



中文翻译:

沸石膜:比较H 2 O / H 2 / CO 2混合物的分离和测试将CO 2加氢成甲醇的反应器

可以使用沸石膜反应器将CO 2加氢为甲醇。从反应环境中除去水将增加反应速率和可达到的转化率。用几种沸石膜(沸石A,丝光沸石,沸石T,菱沸石和钛菱沸石)测试在适合于该反应的温度下从含有CO 2,氢和水的混合物中分离水的能力。沸石A提供了最佳的H 2 O / H 2分离因子。初步实验比较了传统反应器和传统反应器与膜反应器的组合,结果表明甲醇的收率得到提高,在一种情况下,甲醇的收率高于常规反应器中对应于热力学平衡的极限。

更新日期:2020-03-19
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