Two new Zn(II)-containing coordination polymers of {[NH₂(CH₃)₂][Zn_1.5(abtc)]·H₂O}_n (1) and {[Zn₂(abtc)(DMF)₃]·3DMF}_n (2) have been produced under the solvothermal conditions by using the 3,3′,5,5′-azobenzenetetracarboxylic acid ligand in different solvent systems. Complex 1 and complex 2 can use as the luminescence sensors for the detection of Fe³⁺ which have high selectivity and sensitivity. Furthermore, the mechanism for the luminescent sensing of Fe³⁺ was also suggested. In the bio-research, the treatment activity for compounds 1 and 2 on SCAD was assessed through serious researches and the specific mechanism was discussed as well. After the construction of the SCAD rat model, the 5 mg/kg compounds 1 and 2 was given to the rats for treatment. The ELISA detection kit was used for the IL-17 content detection in the plasma of different groups. And, the abundance of the E.coli in the intestinal flora was detected with RT-PCR.

{[NH ₂（CH ₃）₂ ] [Zn _1.5（abtc）]·H ₂ O} _n（1）和{[Zn ₂（abtc）（DMF）₃ ]的两种新型含Zn（II）配位聚合物·通过在不同溶剂体系中使用3,3'，5,5'-偶氮苯四羧酸配体在溶剂热条件下制备了·3DMF} _n（2）。配合物1和配合物2可用作具有高选择性和灵敏度的用于检测Fe ³⁺的发光传感器。此外，Fe ³⁺的发光传感机理也有人建议。在生物研究中，通过认真的研究评估了化合物1和2对SCAD的治疗活性，并讨论了其具体机制。在建立SCAD大鼠模型后，将5 mg / kg的化合物1和2给予大鼠进行治疗。ELISA检测试剂盒用于不同组血浆中IL-17含量的检测。并且，通过RT-PCR检测到肠道菌群中大肠杆菌的丰度。