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Ring opening polymerization of macrocyclic oligoesters derived from renewable sources
Polymer Chemistry ( IF 4.1 ) Pub Date : 2020-03-17 , DOI: 10.1039/d0py00258e Antxon Martínez de Ilarduya 1, 2, 3, 4, 5 , Sebastián Muñoz Guerra 1, 2, 3, 4, 5
Polymer Chemistry ( IF 4.1 ) Pub Date : 2020-03-17 , DOI: 10.1039/d0py00258e Antxon Martínez de Ilarduya 1, 2, 3, 4, 5 , Sebastián Muñoz Guerra 1, 2, 3, 4, 5
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Macrocyclic oligoesters (MCOs) derived from biomass such as those prepared from alkylene alkanedioates and 2,5-furandicarboxylates are suitable compounds for ring opening polymerization (ROP) to produce high molecular weight bio-based polyesters. The synthetic procedures that have been recently developed to obtain these MCOs in good yields, their ROP either alone or together with other cyclic compounds, and their recovery by cyclodepolymerization of the final polyesters are the main topics covered in this review. Both organometallic compounds and enzymes such as Candida antarctica lipase B are the catalytic systems used for all reactions. This synthetic approach based on ROP of MCOs derived from renewable sources opens a green pathway for a circular economy in plastics.
中文翻译：
衍生自可再生资源的大环低聚酯的开环聚合
源自生物质的大环低聚酯（MCO），例如由亚烷基链烷二酸酯和2,5-呋喃二甲酸酯制备的那些，是适用于开环聚合（ROP）以生产高分子量生物基聚酯的化合物。最近已开发出以高收率获得这些MCO的合成程序，其ROP单独或与其他环状化合物一起以及通过最终聚酯的环解聚回收它们的ROP是本综述的主要主题。有机金属化合物和酶（例如南极假丝酵母脂肪酶B）都是用于所有反应的催化体系。这种基于可再生能源衍生的MCO的ROP的合成方法为塑料循环经济开辟了一条绿色道路。
更新日期：2020-03-17
中文翻译：
衍生自可再生资源的大环低聚酯的开环聚合
源自生物质的大环低聚酯（MCO），例如由亚烷基链烷二酸酯和2,5-呋喃二甲酸酯制备的那些，是适用于开环聚合（ROP）以生产高分子量生物基聚酯的化合物。最近已开发出以高收率获得这些MCO的合成程序，其ROP单独或与其他环状化合物一起以及通过最终聚酯的环解聚回收它们的ROP是本综述的主要主题。有机金属化合物和酶（例如南极假丝酵母脂肪酶B）都是用于所有反应的催化体系。这种基于可再生能源衍生的MCO的ROP的合成方法为塑料循环经济开辟了一条绿色道路。
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