α,ω-Diynes bearing a perfluoroalkylene linker HC≡C(CF₂)_nC≡H (n = 4,6) were obtained from commercially available α,ω-dienes H₂C=CH(CF₂)_nCH=CH₂ via bromination and dehydrobromination. In the presence of CoCl₂-Zn-ZnI₂ catalyst, the diyne HC≡C(CF₂)₄C≡H underwent [2+2+2] cycloaddition reactions with terminal alkynes to afford benzene derivatives fused with an octafluorocyclohexene moiety. In this reaction, trimerization of the diyne was observed as a major side reaction. Rh-catalyzed aromatization polymerization of the diyne HC≡C(CF₂)₆C≡H afforded an insoluble polymer consisting of a densely cross-linked, aromatic skeleton, which was characterized by solid-state CP-MAS ¹³C NMR and IR spectroscopy. This insoluble polymer exhibited high thermal stability, and engineering applications of the product polymer are being evaluated.

α，ω-二炔轴承的全氟亚接头HC≡C（CF ₂）_ñ C≡H（N = 4,6）是由市售的α，ω二烯h条件₂ C = CH（CF ₂）_Ñ CH = CH ₂通过溴化和脱氢溴化。在氯化钴的存在下₂ -Zn-ZnI ₂催化剂中，二炔HC≡C（CF ₂）₄ C≡H后行[2 + 2 + 2]与末端炔烃，得到与octafluorocyclohexene部分稠合的苯衍生物环加成反应。在该反应中，观察到二炔的三聚是主要的副反应。二炔HC≡C（CF ₂）_6的Rh催化芳构化聚合C≡H得到由致密交联的芳族骨架组成的不溶聚合物，其通过固态CP-MAS ¹³ C NMR和IR光谱表征。这种不溶性聚合物表现出高的热稳定性，并且正在评估产物聚合物的工程应用。