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Effects of various rare-earth additives on the sintering and transmittance of γ-AlON
Journal of the European Ceramic Society ( IF 5.8 ) Pub Date : 2020-03-17 , DOI: 10.1016/j.jeurceramsoc.2020.03.027
Ayman Muhammad Tsabit , Myung-Dong Kim , Dang-Hyok Yoon

Several rare earth elements (Sc, La, Pr, Sm, Gd, Dy, Er, and Yb) were evaluated to develop a sintering additive for transparent γ-AlON. After adding 0.2 wt. % of each of the rare earth additives to the α-Al2O3 and AlN starting material, hot pressing was performed at 1850 °C for 1 h under 20 MPa as a screening test, whereby the γ-AlON with Pr-nitrate showed the highest transmittance of 60.4 % at 632 nm. Two-step pressureless sintering was conducted as a separate test for the same starting material after adjusting the amount of Pr-nitrate to 0, 0.1, or 0.2 wt. % to enhance transmittance. The γ-AlON with 0.1 wt. % Pr-nitrate showed the highest transmittance of 80.36 % after 1st and 2nd sintering steps at 1610 and 1940 °C, respectively, indicating that Pr can be an alternative sintering additive to conventional Y2O3, MgO, and La2O3 for the fabrication of transparent γ-AlON.



中文翻译:

各种稀土添加剂对γ-AlON烧结及透射率的影响

对几种稀土元素(Sc,La,Pr,Sm,Gd,Dy,Er和Yb)进行了评估,以开发用于透明γ-AlON的烧结添加剂。加入0.2重量%后。每个稀土添加剂加入的%的α-Al 2 ö 3对于AlN原料,在20MPa,1850℃,1h的条件下进行热压,作为屏蔽试验,γ-AlON与Pr-硝酸盐在632nm下显示出最高的透过率60.4%。在将硝酸硝酸Pr的含量调整为0、0.1或0.2 wt。%的条件下,对同一原材料进行两步无压烧结作为单独的测试。%以提高透射率。具有0.1重量%的γ-AlON。硝酸硝酸铵%分别在1610和1940°C的第一和第二烧结步骤后显示出最高的透光率80.36%,这表明Pr可以替代传统的Y 2 O 3,MgO和La 2 O 3作为烧结添加剂。透明γ-AlON的制备。

更新日期:2020-03-17
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