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The selective heavy metal ions adsorption of zinc oxide nanoparticles from dental wastewater
Chemical Physics ( IF 2.0 ) Pub Date : 2020-03-17 , DOI: 10.1016/j.chemphys.2020.110750
Mengqin Gu , Liying Hao , Yigan Wang , Xiyu Li , Yifan Chen , Wei Li , Li Jiang

Zinc oxide nanoparticles (ZnO-NPs) was synthesized using the traditional hydrothermal method and its characterization as well as adsorption performance of heavy metal ions were studied. X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) confirmed hexagonal structures and functional groups. N2 adsorption-desorption techniques suggested the Brunauer-Emmett-Teller (BET) specific surface area was 26.777 m2/g, indicating the potential in removal process. Scanning electron microscopy-energy dispersive X-ray (SEM-EDX) further ensured the possible interactions of ZnO-NPs and heavy metal ions. Batch adsorption experiments showed higher affinity towards Cr3+, and the maximal adsorption capacity was 88.547 mg/g at the optimum conditions (pH 3–7, 1 g/L adsorbent, 20 min contacting time, and 20 mg/L initial Cr3+ ions). The adsorption process showed best fit with the pseudo-second-order and Langmuir isotherm model, suggesting a chemisorption procedure and monolayer type removal. The ZnO-NPs could remove Cr3+ ions selectively, and hold the potential application for dental wastewater purification treatment.



中文翻译:

牙科废水中重金属离子的选择性吸附。

采用传统的水热法合成了氧化锌纳米颗粒(ZnO-NPs),并对其表征以及对重金属离子的吸附性能进行了研究。X射线衍射(XRD)和傅立叶变换红外(FT-IR)证实了六边形结构和官能团。N 2吸附-解吸技术表明,Brunauer-Emmett-Teller(BET)的比表面积为26.777 m 2 / g,表明了去除过程中的潜力。扫描电子显微镜-能量色散X射线(SEM-EDX)进一步确保了ZnO-NP与重金属离子的可能相互作用。分批吸附实验表明对Cr 3+具有更高的亲和力在最佳条件下(pH 3-7、1 g / L吸附剂,20分钟接触时间和20 mg / L初始Cr 3+离子),最大吸附容量为88.547 mg / g 。吸附过程显示出最适合拟二阶和Langmuir等温模型,表明化学吸附程序和单层类型去除。ZnO-NPs可以选择性去除Cr 3+离子,在牙科废水净化处理中具有潜在的应用前景。

更新日期:2020-03-19
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