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Electrochemical evaluation of textile industry waste derived carbon particles for UV-cured epoxy composites
Diamond and Related Materials ( IF 4.1 ) Pub Date : 2020-05-01 , DOI: 10.1016/j.diamond.2020.107804
Muhammad Atif , Abd Ur Rehman Kashif , Zubair Khaliq , Asif Mahmood , Muhammad Asif Hussain , Roberta Bongiovanni

Abstract A facile thermal approach has been applied to recycle industrial waste into Carbon Particles (CPs). Synthesized CPs have been characterized through chemical and instrumental analysis including X-ray Photoelectron Spectroscopy (XPS), Attenuated Total Reflectance (ATR), Scanning Electron Microscopy (SEM), Thermal gravimetric analysis (TGA), Differential Scanning Calorimetry (DSC), Dynamic light scattering (DLS), Cyclic Voltammetry (CV). Evaluation of CPs' conductive behavior has shown a wide range of specific capacitance from 0.977 to 102 mC, with effective electrochemical surface area from 3.49 to 359.95 cm2. A sustainable competence of CPs to carry voltage against time has also been observed. CPs upon utilization as reinforcing agents in UV-cured epoxy composites, have not only drove conductive behavior of composites but have also boosted reaction kinetics and curing conversion. Thermal stability of composites has been found increased, by incorporation of CP. DC conductivity of CP-Epoxy composites have been observed up to 5 folds higher (2.07 × 10−4 Ω−1 cm−1) than neat epoxy (4.91 × 10−9 Ω−1 cm−1).

中文翻译:

纺织工业废料衍生碳颗粒用于紫外固化环氧复合材料的电化学评价

摘要 一种简便的热方法已被应用于将工业废物回收成碳颗粒 (CP)。合成的 CP 已通过化学和仪器分析进行表征,包括 X 射线光电子能谱 (XPS)、衰减全反射 (ATR)、扫描电子显微镜 (SEM)、热重分析 (TGA)、差示扫描量热法 (DSC)、动态光散射 (DLS)、循环伏安法 (CV)。对 CP 导电行为的评估表明,比电容范围很广,从 0.977 到 102 mC,有效电化学表面积从 3.49 到 359.95 cm2。还观察到 CP 具有随时间携带电压的可持续能力。CP 在紫外固化环氧复合材料中用作增强剂,不仅推动了复合材料的导电行为,而且还提高了反应动力学和固化转化率。已发现复合材料的热稳定性通过掺入 CP 得到提高。已观察到 CP-Epoxy 复合材料的 DC 电导率比纯环氧树脂 (4.91 × 10-9 Ω-1 cm-1) 高 5 倍 (2.07 × 10−4 Ω−1 cm−1)。
更新日期:2020-05-01
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