The optical spectroscopy of Bi3+ in d10-based post transition metal oxides (i. e. gallates, germanates, antimonates indates, stannates) is reviewed and analyzed in the frame of empirical models. 20 different compounds are examined. From this, a methodology is introduced to identify the preferred doping sites for Bi3+ and predict the intra- or extra-ionic origin of the Bi3+ emission in these systems. Further, the emission process in calcite-structured InBO3:Bi and GaBO3:Bi is reconsidered.

中文翻译：

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关于 d10 后过渡金属氧化物中 Bi3+ 的光谱

在经验模型的框架内审查和分析了基于 d10 的过渡金属氧化物（即镓酸盐、锗酸盐、锑酸盐、锡酸盐）中 Bi3+ 的光谱。检查了 20 种不同的化合物。由此，引入了一种方法来确定 Bi3+ 的首选掺杂位点，并预测这些系统中 Bi3+ 发射的离子内或离子外来源。此外，重新考虑方解石结构的 InBO3:Bi 和 GaBO3:Bi 中的发射过程。