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Design and synthesis of novel binuclear ferrocenyl-intercalated graphene oxide and polyaniline nanocomposite for supercapacitor applications
Electrochimica Acta ( IF 5.5 ) Pub Date : 2020-03-17 , DOI: 10.1016/j.electacta.2020.136078
Elmira Payami , Iraj Ahadzadeh , Reza Mohammadi , Reza Teimuri-Mofrad

Various new nanohybrids consisting of 2,2-bis(ethylferrocenyl)propane [B-(EtFc)-Pr] as both battery-type electrode material and good candidate for intercalation between graphene oxide (GO) nanosheets, and GO as a substrate were prepared. According to the electrochemical experiments data, GO-B-(EtFc)-Pr3 nanohybrid with the weight ratio of GO:B-(EtFc)-Pr (1:3) was regarded as the optimum nanohybrid with excellent electrochemical performance. Then, GO-B-(EtFc)-Pr3/PANI nanocomposites with different amounts of polyaniline (PANI) were prepared and investigated by Fourier Transform Infrared Spectroscopy (FT-IR), Cyclic Voltammetry (CV), Galvanostatic Charge-Discharge measurement (GCD), Electrochemical Impedance Spectroscopy (EIS), Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive X-ray (EDX) mapping, and X-ray Diffraction (XRD) analyses. Among different nanocomposites, GO-B-(EtFc)-Pr3/PANI0.5 exhibits a high charge storage capacity of 429 mAh g-1 and excellent cycle life with charge storage capacity retention of 89.13 % after 3000 CV cycles.



中文翻译:

用于超级电容器的新型双核二茂铁基插入氧化石墨烯和聚苯胺纳米复合材料的设计与合成

制备了由2,2-双(乙基二茂铁基)丙烷[B-(EtFc)-Pr]作为电池型电极材料和氧化石墨烯(GO)纳米片之间插入的良好候选物以及以GO为底物的各种新型纳米复合物。根据电化学实验数据,GO:B-(EtFc)-Pr(1:3)的重量比的GO-B-(EtFc)-Pr3纳米杂化物被认为是电化学性能优异的最佳纳米杂化物。然后,制备了具有不同量聚苯胺(PANI)的GO-B-(EtFc)-Pr3 / PANI纳米复合材料,并通过傅立叶变换红外光谱(FT-IR),循环伏安法(CV),恒电流充放电测量(GCD)进行了研究。 ),电化学阻抗谱(EIS),场发射扫描电子显微镜(FESEM),能量色散X射线(EDX)映射,和X射线衍射(XRD)分析。在不同的纳米复合材料中,GO-B-(EtFc)-Pr3 / PANI0.5表现出429 mAh g的高电荷存储容量-1和出色的循环寿命,在3000 CV循环后保持89.13%的电荷存储容量。

更新日期:2020-03-19
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