Free‐Radical‐Promoted Alkenylation of C(sp3)−H Bond in Chloroalkane with Cinnamic Acid and β‐Nitrostyrene,Advanced Synthesis & Catalysis

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Free‐Radical‐Promoted Alkenylation of C(sp3)−H Bond in Chloroalkane with Cinnamic Acid and β‐Nitrostyrene
Advanced Synthesis & Catalysis ( IF 4.4 ) Pub Date : 2020-03-15 , DOI: 10.1002/adsc.202000215
Minzhi Sun ₁ , Zhengbao Xu ₂ , Wenjie Li ₁ , Le Yang ₁ , Huichao You ₁ , Dan Yu ₁ , Fang Fang ₁ , Yaxin Wang ₁ , Zhong‐Quan Liu ₁

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We demonstrated herein a free‐radical alkenylation of the C(sp ³)−H bond in 1,2‐dichloroethane with cinnamic acid and β ‐nitrostyrene. This method not only provides a facile approach to chloroalkylated styrenes, but also would be instructive for halogen‐atom directing selective functionalization of inert C(sp ³)−H bond.

中文翻译：

肉桂酸和β-硝基苯乙烯在氯代烷烃中自由基促进的C（sp3）-H键的烯基化

我们在这里证明了1,2-二氯乙烷中肉桂酸和β-硝基苯乙烯的C（sp ³）-H键的自由基烯基化。该方法不仅为氯烷基化的苯乙烯提供了一种简便的方法，而且对于指导卤素原子指导惰性C（sp ³）-H键的选择性官能化具有指导意义。

更新日期：2020-03-15

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