Synthesis and study of Fe → Pd interactions in unsymmetric Pd(II) complexes with phosphinoferrocene guanidine ligands,Dalton Transactions

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Synthesis and study of Fe → Pd interactions in unsymmetric Pd(II) complexes with phosphinoferrocene guanidine ligands
Dalton Transactions ( IF 3.5 ) Pub Date : 2020/03/16 , DOI: 10.1039/d0dt00812e
Ondřej Bárta _{1,

2,

3,

4,

5} , Róbert Gyepes _{1,

2,

3,

4,

5} , Ivana Císařová _{1,

2,

3,

4,

5} , Adam Alemayehu _{1,

2,

3,

4,

5} , Petr Štěpnička _{1,

2,

3,

4,

5}

Affiliation

Readily available phosphinoferrocene guanidines coordinate Pd(II) as P,N-chelating or κ³P,N,Fe-bound ligands. As the latter, they give rise to the first donor-asymmetric complexes featuring Fe–Pd dative bonds, which were studied using direct (spectroscopic and electrochemical) methods and theoretical (DFT) approaches.

中文翻译：

具有膦二茂铁胍配体的不对称Pd（II）配合物中Fe→Pd相互作用的合成与研究

容易获得的phosphinoferrocene胍坐标的Pd（II）为P，N-螯合或κ ³ P，N，Fe基结合的配体。作为后者，它们产生了第一个具有Fe-Pd配位键的供体不对称络合物，已使用直接（光谱和电化学）方法和理论（DFT）方法进行了研究。

更新日期：2020-04-08

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