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Insight in the relationship between magnetism of stoichiometric spinel ferrites and their catalytic activity
Catalysis Communications ( IF 3.4 ) Pub Date : 2020-03-16 , DOI: 10.1016/j.catcom.2020.105986
Ji Ma , Chunting Liu , Kezheng Chen

In this work, spinel ferrites were chosen as prototype systems for oxidative dehydrogenation of 1-butene to address the long-standing issue that whether there is a correlation between catalytic and magnetic properties of magnetic catalysts. Under zero magnetic field, the conversion was the largest for NiFe2O4 (74.5 mol%) and the least for ZnFe2O4 (12.6 mol%), with no quantative relationship between magnetism and catalytic activity. In contrast, under a magnetic field of 1603 Oe, the largest and least conversion values changed to 86.6 and 13.5 mol% for MgFe2O4 and ZnFe2O4, respectively, and these values exhibited an inverse Gauss relation with initial susceptibility.



中文翻译:

洞察化学计量尖晶石铁氧体的磁性与其催化活性之间的关系

在这项工作中,选择尖晶石铁氧体作为1-丁烯氧化脱氢的原型系统,以解决长期存在的问题,即磁性催化剂的催化性能和磁性之间是否存在相关性。在零磁场下,NiFe 2 O 4的转化率最大(74.5 mol%),而ZnFe 2 O 4的转化率最小(12.6 mol%),磁性与催化活性之间没有定量关系。相反,在1603 Oe的磁场下,MgFe 2 O 4和ZnFe 2 O 4的最大和最小转换值变为86.6和13.5 mol%,并且这些值与初始磁化率呈反高斯关系。

更新日期:2020-03-16
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