Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy ( IF 4.4 ) Pub Date : 2020-03-16 , DOI: 10.1016/j.saa.2020.118256 Swastika Dhar , Buddhadeb Sen , Subhra Kanti Mukhopadhyay , Trinetra Mukherjee , Asoke Prasun Chattopadhyay , Sadhan Pramanik
Polyvinyl-pyrrolidone capped spherical cadmium sulphide quantum dots (CdS-PVP QDs), 2–6 nm in size, were developed as a selective turn-on fluorescence nanosensor for monohydrogen phosphate ion (HPO42−) in aqueous medium. Fluorescence intensity of CdS-PVP QDs significantly increased with addition of HPO42− ions, whereas the other common inorganic ions had very little effect on the fluorescence intensity. The proposed sensor may be efficiently used for the detection of HPO42− ions at a low level of concentration up to 213 nM in real urine sample. Cell imaging study indicates that the CdS-PVP QDs are cell permeable and can detect the intracellular distribution of HPO42− ions under fluorescence microscope. The CdS-PVP QDs showed considerable activity against Staphylococcus aureus also.
中文翻译:
嵌入PVP中的CdS量子点:真实样品中的无机磷酸根离子感测及其抗菌活性
聚乙烯吡咯烷酮封端的球形硫化镉量子点(CdS-PVP QDs),尺寸为2-6 nm,是一种选择性开启荧光纳米传感器,用于水性介质中的磷酸一氢离子(HPO 4 2-)。添加HPO 4 2-离子后,CdS-PVP QD的荧光强度显着增加,而其他常见的无机离子对荧光强度的影响很小。所提出的传感器可以有效地用于检测尿液中浓度高达213 nM的低浓度HPO 4 2-离子。细胞成像研究表明CdS-PVP QD具有细胞渗透性,可以检测HPO 4 2-的细胞内分布离子在荧光显微镜下。CdS-PVP QDs也显示出抗金黄色葡萄球菌的活性。