Low cost carbon materials gained extensive attention in the field of sustainable energy storage devices. A major challenge in assembly of fluorine doped tin oxide (FTO) glass free dye sensitized solar cell (DSSC) is the heat treatment limitation and transparency of electrodes. In this work, a rational design of a carbon composite dye-sensitized solar cell (CC-DSSC) fabricated with stacking carbon fiber wet-laid web (CF_W) is described. The front electrode is prepared by a fibrous thin sheet of carbon fibers deposited with extended Titania nanorods (e-TiO₂ nR). Whereas, the counter electrode is prepared by the composite of CF and exfoliated graphite micro platelets (Ex-GMP). The assembled CC-DSSC demonstrated 5.207% efficiency with high fill factor (FF) and open-circuit voltage (V_OC). The high V_OC of designed CC-DSSC ascribed to the high transmittance (50%), sheet conductivity and efficient charge generation of e-TiO₂ nR/CF_W electrode. Moreover, e-TiO₂ nR provides high dye absorption and electron mobility suitable for the CF_W substrate. Alternatively, high FF of CC-DSSC provides evidence of remarkable electrocatalytic activity and low charge transfer resistance (1.915 Ω) of the Ex-GMP/CF_W CE system. Our proposed system of carbon composite DSSC will provide new ways towards the fabrication of sustainable and low-cost energy storage devices.

低成本碳材料在可持续储能设备领域引起了广泛关注。组装氟掺杂氧化锡（FTO）无玻璃染料敏化太阳能电池（DSSC）的主要挑战是电极的热处理限制和透明性。在这项工作中，描述了碳纤维湿法成网（CF _W）堆叠而成的碳复合染料敏化太阳能电池（CC-DSSC）的合理设计。前电极由沉积有扩展的Titania纳米棒（e-TiO ₂ nR）的碳纤维纤维薄片制成。而对电极则由CF和片状石墨微片（Ex-GMP）的复合材料制成。组装的CC-DSSC在高填充系数（FF）和开路电压（V_OC）。设计的CC-DSSC的高V _OC可归因于e-TiO ₂ nR / CF _W电极的高透射率（50％），薄层电导率和高效电荷产生。此外，e-TiO ₂ nR提供了适合CF _W基板的高染料吸收和电子迁移率。另外，CC-DSSC的高FF提供了Ex-GMP / CF _W CE系统出色的电催化活性和低的电荷转移电阻（1.915Ω）的证据。我们提出的碳复合材料DSSC系统将为制造可持续的低成本储能设备提供新的途径。