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A universal reactor platform for batch and flow: application to homogeneous and heterogeneous hydrogenation
Reaction Chemistry & Engineering ( IF 3.9 ) Pub Date : 2020-03-13 , DOI: 10.1039/d0re00061b
Fanfu Guan 1, 2, 3, 4, 5 , Nikil Kapur 3, 4, 5, 6 , Louise Sim 3, 4, 5, 7 , Connor J. Taylor 3, 4, 5, 8 , Jialin Wen 9, 10, 11, 12 , Xumu Zhang 9, 10, 11, 12 , A. John Blacker 1, 2, 3, 4, 5
Affiliation  

An array of miniature 1.7 mL, 9 bar pressure-rated continuous stirred tank reactors (CSTRs) have been developed and used to determine optimal hydrogenation conditions in batch, before being reconfigured to carry out the hydrogenation in continuous flow. On-line pressure measurement was used to give direct mass transfer kinetics. The system has been tested using benchmark heterogeneous and homogenous reactions in batch and flow. The simplicity of the system enables chemists to overcome problems that are associated with carrying-out pressure hydrogenations.

中文翻译:

适用于分批加料的通用反应器平台:应用于均相和非均相加氢

已经开发了一系列微型1.7 mL,9 bar额定压力的连续搅拌釜反应器(CSTR),用于批量确定最佳氢化条件,然后将其重新配置为以连续流进行氢化。在线压力测量用于给出直接的传质动力学。该系统已使用批次和流程中的基准异质和均质反应进行了测试。该系统的简单性使化学家能够克服与进行压力氢化相关的问题。
更新日期:2020-03-13
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